FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1964558512> ?p ?o ?g. }

• W1964558512 endingPage "163" @default.
• W1964558512 startingPage "151" @default.
• W1964558512 abstract "In order to obtain highly dispersed heteropolyacid species, H3PW12O40 (HPA) was supported on various silica-based supports. Three lamellar silicates were used: a natural montmorillonite with high alkaline metal content, an `activated' montmorillonite strongly delaminated with low alkaline metal content, a kenyaite which is a lamellar sodium silicate as well as a mesoporous hexagonal silica (HMS). The state of the supported HPA was studied by X-ray diffraction, molecular spectroscopies, HRTEM and EDX-STEM and particularly by their catalytic behavior in the methanol conversion, which is considered as a bulk-type reaction, and in the n-butane isomerization considered as a surface-type reaction. The presence of a high content of charge compensating alkaline cations in the lamellar structures was shown to decompose the Keggin structure, leading to solids with poor acidic properties. The influence of the HPA content, ranging between 10 and 50 wt%, was studied on the `activated' montmorillonite. An exchange reaction between the charge compensating cations of the clay and the protons of the HPA was shown to occur for low HPA content. The Keggin structure was preserved, but the dispersion was not as high as on the mesoporous silica, and the presence of residual charge compensating cations decreased the catalytic activities. The HPA/HMS sample was highly active for the two reactions and we suggest that for this sample the catalytic activity was due to isolated HPA molecules entrapped within the pores." @default.
• W1964558512 created "2016-06-24" @default.
• W1964558512 creator A5037477689 @default.
• W1964558512 creator A5046817972 @default.
• W1964558512 creator A5084658897 @default.
• W1964558512 date "1998-06-01" @default.
• W1964558512 modified "2023-09-27" @default.
• W1964558512 title "Acid-type catalytic properties of heteropolyacid H3PW12O40 supported on various porous silica-based materials" @default.
• W1964558512 cites W1966210407 @default.
• W1964558512 cites W1971251631 @default.
• W1964558512 cites W1977582882 @default.
• W1964558512 cites W1978082497 @default.
• W1964558512 cites W1979482539 @default.
• W1964558512 cites W1981017446 @default.
• W1964558512 cites W1989493103 @default.
• W1964558512 cites W1990179013 @default.
• W1964558512 cites W1992509636 @default.
• W1964558512 cites W1993411495 @default.
• W1964558512 cites W1995825299 @default.
• W1964558512 cites W2011221361 @default.
• W1964558512 cites W2012664774 @default.
• W1964558512 cites W2014474525 @default.
• W1964558512 cites W2015787344 @default.
• W1964558512 cites W2017063205 @default.
• W1964558512 cites W2018358842 @default.
• W1964558512 cites W2024545529 @default.
• W1964558512 cites W2025721238 @default.
• W1964558512 cites W2029605038 @default.
• W1964558512 cites W2038464558 @default.
• W1964558512 cites W2041484191 @default.
• W1964558512 cites W2041525724 @default.
• W1964558512 cites W2041554845 @default.
• W1964558512 cites W2045573478 @default.
• W1964558512 cites W2053824506 @default.
• W1964558512 cites W2057472192 @default.
• W1964558512 cites W2064473740 @default.
• W1964558512 cites W2065807815 @default.
• W1964558512 cites W2067442875 @default.
• W1964558512 cites W2073235332 @default.
• W1964558512 cites W2073348783 @default.
• W1964558512 cites W2090433510 @default.
• W1964558512 cites W2334199795 @default.
• W1964558512 cites W2949159389 @default.
• W1964558512 cites W2949870170 @default.
• W1964558512 cites W2951912048 @default.
• W1964558512 cites W36638892 @default.
• W1964558512 doi "https://doi.org/10.1016/s1387-1811(98)00089-4" @default.
• W1964558512 hasPublicationYear "1998" @default.
• W1964558512 type Work @default.
• W1964558512 sameAs 1964558512 @default.
• W1964558512 citedByCount "117" @default.
• W1964558512 countsByYear W19645585122012 @default.
• W1964558512 countsByYear W19645585122013 @default.
• W1964558512 countsByYear W19645585122014 @default.
• W1964558512 countsByYear W19645585122015 @default.
• W1964558512 countsByYear W19645585122016 @default.
• W1964558512 countsByYear W19645585122017 @default.
• W1964558512 countsByYear W19645585122018 @default.
• W1964558512 countsByYear W19645585122019 @default.
• W1964558512 countsByYear W19645585122021 @default.
• W1964558512 countsByYear W19645585122022 @default.
• W1964558512 crossrefType "journal-article" @default.
• W1964558512 hasAuthorship W1964558512A5037477689 @default.
• W1964558512 hasAuthorship W1964558512A5046817972 @default.
• W1964558512 hasAuthorship W1964558512A5084658897 @default.
• W1964558512 hasConcept C127413603 @default.
• W1964558512 hasConcept C161790260 @default.
• W1964558512 hasConcept C178790620 @default.
• W1964558512 hasConcept C179104552 @default.
• W1964558512 hasConcept C185592680 @default.
• W1964558512 hasConcept C2777496208 @default.
• W1964558512 hasConcept C2777515222 @default.
• W1964558512 hasConcept C2779607525 @default.
• W1964558512 hasConcept C42360764 @default.
• W1964558512 hasConcept C77851909 @default.
• W1964558512 hasConcept C8010536 @default.
• W1964558512 hasConcept C82776694 @default.
• W1964558512 hasConceptScore W1964558512C127413603 @default.
• W1964558512 hasConceptScore W1964558512C161790260 @default.
• W1964558512 hasConceptScore W1964558512C178790620 @default.
• W1964558512 hasConceptScore W1964558512C179104552 @default.
• W1964558512 hasConceptScore W1964558512C185592680 @default.
• W1964558512 hasConceptScore W1964558512C2777496208 @default.
• W1964558512 hasConceptScore W1964558512C2777515222 @default.
• W1964558512 hasConceptScore W1964558512C2779607525 @default.
• W1964558512 hasConceptScore W1964558512C42360764 @default.
• W1964558512 hasConceptScore W1964558512C77851909 @default.
• W1964558512 hasConceptScore W1964558512C8010536 @default.
• W1964558512 hasConceptScore W1964558512C82776694 @default.
• W1964558512 hasIssue "1-3" @default.
• W1964558512 hasLocation W19645585121 @default.
• W1964558512 hasLocation W19645585122 @default.
• W1964558512 hasLocation W19645585123 @default.
• W1964558512 hasOpenAccess W1964558512 @default.
• W1964558512 hasPrimaryLocation W19645585121 @default.
• W1964558512 hasRelatedWork W1978035409 @default.
• W1964558512 hasRelatedWork W2018726308 @default.
• W1964558512 hasRelatedWork W2120731426 @default.

• next