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- W1964575700 abstract "An original method of determination of the thermal ionization energy (TIE) of monovalent centres in the crystals with persistent non-equilibrium conductivity is presented. It is based on the analysis of the correlation between conductivity σ and a quantity α proportional to the number of the electrons bound on the centres, simultaneously measured at constant temperature. The method is applied to the determination of the TIE of Y3+ centres is unconverted CdF2: YF3 crystals. After UV excitation conductivity and IR absorption typical for M3+ centres is simultaneously measured at 77 K. Values of TIE of E01 = 125 meV and E02 = 98 meV are obtained.Es wird eine neuartige Methode zur Bestimmung der thermischen Ionisationsenergie (TIE) von einwertigen Zentren in Kristallen mit standiger Nichtgleichgewichtsleitfahigkeit angegeben. Sie beruht auf der Analyse der Korrelation zwischen Leitfahigkeit σ und einer Grose α, die proportional zur Anzahl der Elektronen ist, die an den Zentren gebunden sind, und die gleichzeitig bei konstanter Temperatur gemessen wird. Die Methode wird zur Bestimmung der TIE von Y3+-Zentren in nichtkonvertierten CdF2: YF3-Kristallen angewendet. Nach UV-Anregung wird Leitfahigkeit und IR-Absorption, typisch fur M3+-Zentren, gleichzeitig bei 77 K gemessen. Werte fur TIE von E01 = 125 meV und E02 = 98 meV werden erhalten." @default.
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- W1964575700 date "1980-05-16" @default.
- W1964575700 modified "2023-09-28" @default.
- W1964575700 title "Experimental determination of the thermal ionization energy of monovalent centres in crystals with persistent non-equilibrium conductivity application to CdF2:YF3" @default.
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- W1964575700 doi "https://doi.org/10.1002/pssa.2210590136" @default.
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