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- W1964579426 abstract "1-(2'-Pyrido and 2'-quinolino)-(1R)-arylethylamino)-ethylidenes (7-12) were prepared as potential ligands in Pd Η catalytic complexes for enantioselective allylic alkylation of 1,3-diphenyl-1-acetoxy-propene-2 (15). Alkylation with palladium complexes of 7-12 yielded 1,3-diphenyl-l-dimethylmalonyl-propene-2 (14) with enantioselectivity up to 55 % e.e. Enantioselectivity is discussed in view of the results recently reported for structurally related 1,5-bidentate dinitrogen ligands of C 1 symmetry. Reversal of enantioselectivity observed for the ligands 10 and 11 is attributed to the inversion of steric requirements in the second coordination sphere of their catalytic complexes." @default.
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- W1964579426 date "2004-02-10" @default.
- W1964579426 modified "2023-10-18" @default.
- W1964579426 title "Comparative Study of 1,5-Dinitrogen Schiff Bases as Potential Ligands in Palladium-Catalyzed Allylic Alkylation." @default.
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- W1964579426 doi "https://doi.org/10.1002/chin.200406017" @default.
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