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• W1964588052 abstract "Electron beam initiated grafting of trimethylol propane triacrylate (TMPTA) onto ethylene propylene diene monomer (EPDM) has been carried out over a wide range of irradiation doses (0–200 kGy) using a fixed concentration (10%) of TMPTA. The samples have been both surface and bulk modified. Infrared (IR) studies indicate increased peak absorbances at 1730, 1260, 1120 and 1019 cm−1 upto 50 kGy and hence increased CO and C–O–C concentrations. The results are further supported by X-ray photoelectron spectroscopy (XPS) studies. The surface energy of EPDM increases from 46.5 to 60.7 mJ/m2 on irradiation of the surface modified samples to 50 kGy dose, due to increased contribution of γSAB and γS(−). The results have been explained with the help of IR and XPS data. The values of tensile strength of the surface modified samples have not changed very significantly, while the moduli values have increased at the cost of the elongation at break. DMTA studies have shown changes in Tg and tan δmax on modification of the surface. The surface morphology of the modified and irradiated samples reveals acrylate flow marks at high magnification." @default.
• W1964588052 created "2016-06-24" @default.
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• W1964588052 date "1998-01-01" @default.
• W1964588052 modified "2023-10-06" @default.
• W1964588052 title "Surface-and bulk-properties of EPDM rubber modified by electron beam irradiation" @default.
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• W1964588052 doi "https://doi.org/10.1016/s0969-806x(97)00296-x" @default.
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