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- W1964598401 abstract "Abstract Molybdenum (Mo) isotopes have great potential as a paleoredox indicator, but this potential is currently restricted by an incomplete understanding of isotope fractionations occurring during key (bio)geochemical processes. To address one such uncertainty we have investigated the isotopic fractionation of Mo during adsorption to a range of Fe (oxyhydr)oxides, under variable Mo/Fe-mineral ratios and pH. Our data confirm that Fe (oxyhydr)oxides can readily adsorb Mo, highlighting the potential importance of this removal pathway for the global Mo cycle. Furthermore, adsorption of Mo to Fe (oxyhydr)oxides is associated with preferential uptake of the lighter Mo isotopes. Fractionations between the solid and dissolved phase (Δ98Mo) increase at higher pH, and also vary with mineralogy, increasing in the order magnetite (Δ98Mo = 0.83 ± 0.60‰)" @default.
- W1964598401 created "2016-06-24" @default.
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- W1964598401 date "2009-11-01" @default.
- W1964598401 modified "2023-10-16" @default.
- W1964598401 title "Mo isotope fractionation during adsorption to Fe (oxyhydr)oxides" @default.
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- W1964598401 doi "https://doi.org/10.1016/j.gca.2009.08.004" @default.
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