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- W1964608017 abstract "A new method that allows a linear drift tube to be operated as a continuous ion mobility filter is described. Unlike conventional ion mobility instruments that use an electrostatic gate to introduce a packet of ions into a drift region, the present approach uses multiple segmented drift regions with modulated drift fields to produce conditions that allow only ions with appropriate mobilities to pass through the instrument. In this way, the instrument acts as a mobility filter for continuous ion sources. By changing the frequency of the applied drift fields it is possible to tune this instrument to transmit ions having different mobilities. A scan over a wide range of drift field frequencies for a single ion species shows a peak corresponding to the expected resonance time of the ions in one drift region segment and a series of peaks at higher frequencies that are overtones of the resonant frequency. The measured resolving power increases for higher overtones, making it possible to resolve structures that were unresolved in the region of the fundamental frequency. We demonstrate the approach by examining oligosaccharide isomers, raffinose and melezitose as well as a mixture of peptides obtained from enzymatic digestion of myoglobin." @default.
- W1964608017 created "2016-06-24" @default.
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- W1964608017 date "2009-05-01" @default.
- W1964608017 modified "2023-10-10" @default.
- W1964608017 title "Overtone mobility spectrometry: Part 1. Experimental observations" @default.
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- W1964608017 doi "https://doi.org/10.1016/j.jasms.2008.11.022" @default.
- W1964608017 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/2709233" @default.
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