Matches in SemOpenAlex for { <https://semopenalex.org/work/W1964613723> ?p ?o ?g. }
Showing items 1 to 93 of
93
with 100 items per page.
- W1964613723 endingPage "1469" @default.
- W1964613723 startingPage "1456" @default.
- W1964613723 abstract "Five cyclopentanones were prepared for the purpose of examining the effects of stereogenic centers on the course of the intramolecular [4 + 3] cycloaddition reactions of cyclopentenyl cations. One substrate reacted with very high levels of diastereoselectivity and was converted to (+)-dactylol. The cyclopentenone without stereogenic centers on the tether or the five-membered ring gave two cycloadducts, the endo isomer being only slightly favored over the exo. Other substrates reacted with generally good to poor stereoselectivity. An epimer of the substrate leading to (+)-dactylol afforded all possible isomers of the cycloadduct with relatively poor stereoselectivity.Key words: cycloaddition, total synthesis, dactylol." @default.
- W1964613723 created "2016-06-24" @default.
- W1964613723 creator A5025902351 @default.
- W1964613723 creator A5043924849 @default.
- W1964613723 creator A5062334556 @default.
- W1964613723 date "2006-10-01" @default.
- W1964613723 modified "2023-10-09" @default.
- W1964613723 title "Intramolecular [4 + 3] cycloadditions – Stereochemical issues in the cycloaddition reactions of cyclopentenyl cations – A synthesis of (+)-dactylol" @default.
- W1964613723 cites W1968305858 @default.
- W1964613723 cites W2004527728 @default.
- W1964613723 cites W2007007072 @default.
- W1964613723 cites W2035456443 @default.
- W1964613723 cites W2042975218 @default.
- W1964613723 cites W2055874107 @default.
- W1964613723 cites W2088113096 @default.
- W1964613723 cites W2089673882 @default.
- W1964613723 cites W2096108123 @default.
- W1964613723 cites W2339661365 @default.
- W1964613723 cites W2950367549 @default.
- W1964613723 cites W2950588917 @default.
- W1964613723 cites W2952535392 @default.
- W1964613723 cites W4252333791 @default.
- W1964613723 doi "https://doi.org/10.1139/v06-122" @default.
- W1964613723 hasPublicationYear "2006" @default.
- W1964613723 type Work @default.
- W1964613723 sameAs 1964613723 @default.
- W1964613723 citedByCount "17" @default.
- W1964613723 countsByYear W19646137232013 @default.
- W1964613723 countsByYear W19646137232014 @default.
- W1964613723 countsByYear W19646137232015 @default.
- W1964613723 countsByYear W19646137232016 @default.
- W1964613723 countsByYear W19646137232017 @default.
- W1964613723 countsByYear W19646137232018 @default.
- W1964613723 countsByYear W19646137232020 @default.
- W1964613723 countsByYear W19646137232021 @default.
- W1964613723 countsByYear W19646137232022 @default.
- W1964613723 crossrefType "journal-article" @default.
- W1964613723 hasAuthorship W1964613723A5025902351 @default.
- W1964613723 hasAuthorship W1964613723A5043924849 @default.
- W1964613723 hasAuthorship W1964613723A5062334556 @default.
- W1964613723 hasConcept C111368507 @default.
- W1964613723 hasConcept C127313418 @default.
- W1964613723 hasConcept C134195300 @default.
- W1964613723 hasConcept C146686406 @default.
- W1964613723 hasConcept C155647269 @default.
- W1964613723 hasConcept C161790260 @default.
- W1964613723 hasConcept C178790620 @default.
- W1964613723 hasConcept C181647583 @default.
- W1964613723 hasConcept C185592680 @default.
- W1964613723 hasConcept C203130289 @default.
- W1964613723 hasConcept C2777289219 @default.
- W1964613723 hasConcept C2777903533 @default.
- W1964613723 hasConcept C2779664164 @default.
- W1964613723 hasConcept C2780378348 @default.
- W1964613723 hasConcept C71240020 @default.
- W1964613723 hasConcept C75079739 @default.
- W1964613723 hasConceptScore W1964613723C111368507 @default.
- W1964613723 hasConceptScore W1964613723C127313418 @default.
- W1964613723 hasConceptScore W1964613723C134195300 @default.
- W1964613723 hasConceptScore W1964613723C146686406 @default.
- W1964613723 hasConceptScore W1964613723C155647269 @default.
- W1964613723 hasConceptScore W1964613723C161790260 @default.
- W1964613723 hasConceptScore W1964613723C178790620 @default.
- W1964613723 hasConceptScore W1964613723C181647583 @default.
- W1964613723 hasConceptScore W1964613723C185592680 @default.
- W1964613723 hasConceptScore W1964613723C203130289 @default.
- W1964613723 hasConceptScore W1964613723C2777289219 @default.
- W1964613723 hasConceptScore W1964613723C2777903533 @default.
- W1964613723 hasConceptScore W1964613723C2779664164 @default.
- W1964613723 hasConceptScore W1964613723C2780378348 @default.
- W1964613723 hasConceptScore W1964613723C71240020 @default.
- W1964613723 hasConceptScore W1964613723C75079739 @default.
- W1964613723 hasIssue "10" @default.
- W1964613723 hasLocation W19646137231 @default.
- W1964613723 hasOpenAccess W1964613723 @default.
- W1964613723 hasPrimaryLocation W19646137231 @default.
- W1964613723 hasRelatedWork W2007438062 @default.
- W1964613723 hasRelatedWork W2161684794 @default.
- W1964613723 hasRelatedWork W2279935933 @default.
- W1964613723 hasRelatedWork W2328950071 @default.
- W1964613723 hasRelatedWork W2765200219 @default.
- W1964613723 hasRelatedWork W2806984475 @default.
- W1964613723 hasRelatedWork W2951270347 @default.
- W1964613723 hasRelatedWork W4253275680 @default.
- W1964613723 hasRelatedWork W4313236524 @default.
- W1964613723 hasRelatedWork W4386564486 @default.
- W1964613723 hasVolume "84" @default.
- W1964613723 isParatext "false" @default.
- W1964613723 isRetracted "false" @default.
- W1964613723 magId "1964613723" @default.
- W1964613723 workType "article" @default.