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- W1964664772 endingPage "1557" @default.
- W1964664772 startingPage "1554" @default.
- W1964664772 abstract "Molecular-based magnets with high magnetic-ordering temperatures, Tc, can be obtained by mild chemistry methods by focusing on the bimetallic and mixed-valence transition metal μ-cyanide of the Prussian blue family. A simple orbital model was used to predict the electronic structure of the metal ions required to achieve a high ordering temperature. The synthesis and magnetic properties of two compounds, [Cr5(CN)12]⋅10H2O and Cs0.75 [Cr2.125(CN)6]⋅5H2O, which exhibited magnetic-ordering temperatures of 240 and 190 kelvin, respectively, are reported, together with the strategy for further work." @default.
- W1964664772 created "2016-06-24" @default.
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- W1964664772 date "1993-12-03" @default.
- W1964664772 modified "2023-10-01" @default.
- W1964664772 title "High- <i>T</i> <sub>c</sub> Molecular-Based Magnets: Ferrimagnetic Mixed-Valence Chromium(III)-Chromium(II) Cyanides with <i>T</i> <sub>c</sub> at 240 and 190 Kelvin" @default.
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- W1964664772 doi "https://doi.org/10.1126/science.262.5139.1554" @default.
- W1964664772 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17829385" @default.
- W1964664772 hasPublicationYear "1993" @default.
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