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• W1964733002 endingPage "132" @default.
• W1964733002 startingPage "126" @default.
• W1964733002 abstract "Abstract Activation of CO2 and acidic C–H bonds by the lutidine-tris(pentafluorophenyl)borane [Lut/B(C6F5)3] frustrated Lewis pair (FLP) are described (lutidine = 2,6-dimethylpyridine). Lut/B(C6F5)3 reacts with CO2 and H2 at ambient temperature and 4 atm of pressure to form the lutidinium boro-formate salt [LutH+][HC( O)OB(C6F5)3−]. This salt has been fully characterized including an X-ray crystal structure and independent synthesis from formic acid and Lut/B(C6F5)3. Attempts to activate a C–H bond in methane by Lut/B(C6F5)3, analogous to its heterolytic cleavage of H2, were unsuccessful, which are consistent with published calculations showing significant barriers to this reaction. Lut/B(C6F5)3 does react with more acidic C–H bonds, including acetone and nitroalkanes. With nitromethane, the boro-nitrone anion H2C NO2B(C6F5)3− is formed, as indicated by NMR and mass spectral analyses." @default.
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• W1964733002 date "2011-04-01" @default.
• W1964733002 modified "2023-10-16" @default.
• W1964733002 title "Metal-free carbon dioxide reduction and acidic C–H activations using a frustrated Lewis pair" @default.
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• W1964733002 doi "https://doi.org/10.1016/j.ica.2010.12.022" @default.
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