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• W1964738065 endingPage "152" @default.
• W1964738065 startingPage "147" @default.
• W1964738065 abstract "Poly- and perfluorinated compounds (PFCs) are a class of global environmental pollutants that are of concern regarding their environmental fate and adverse effects. However, data on the basic physicochemical property of PFCs are still limited. To fill part of the data gaps, temperature-dependent predictive models for vapor pressure of PFCs were developed based on previously reported experimental data. The applicability domain of the models was analyzed using the Williams plot and the influential points and the response outliers were identified. The statistical performance of the models was significantly improved by removing these influential points and response outliers. This procedure confirmed the importance of properly defining the applicability domain of the predictive models. It is shown that the main factors governing the vapor pressure of PFCs, are intermolecular dispersive interactions, hydrogen bonding, temperature, intermolecular dipole-induced dipole interactions and dipole–dipole interactions. Although the model obtained could be used to reliably predict the vapor pressures of certain PFCs at different temperatures, it is essential that the prediction must fall within the applicability domain of the model and the temperature range for reliable predictions." @default.
• W1964738065 created "2016-06-24" @default.
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• W1964738065 date "2013-08-01" @default.
• W1964738065 modified "2023-09-26" @default.
• W1964738065 title "Predictive models for estimating the vapor pressure of poly- and perfluorinated compounds at different temperatures" @default.
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• W1964738065 doi "https://doi.org/10.1016/j.atmosenv.2013.04.042" @default.
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