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- W1964792847 abstract "The deactivation processes of polymethine dimers of DDEOCI (3,3′-diethyl-5,5′-diphenyl-9-ethyl-oxacarbocyanine iodide) have been investigated by means of steady-state and time-resolved absorption spectroscopy. The decay kinetics as well as the transient absorption spectra showing additionally special features of the complex process of polymethine aggregation. The decay kinetics as well as the transient absorption spectra have been analyzed. The kinetical investigations show that the dimer deactivation time is considerably longer than the monomer lifetime due to the hindered rotation of the excited dimer molecule. The transient absorption spectrum is a superposition of the monomer, dimer and J-aggregate spectra which is explained by simultaneous excitation of monomer and dimer components in the dimer band and an energy transfer from the monomer to the J-aggregate." @default.
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- W1964792847 date "1992-03-01" @default.
- W1964792847 modified "2023-09-27" @default.
- W1964792847 title "Picosecond absorption spectroscopy of polymethine dimers" @default.
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- W1964792847 doi "https://doi.org/10.1016/0022-2860(92)80057-o" @default.
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