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• W1964821644 abstract "Abstract 3α,12α‐Dihydroxy‐5β‐cholan‐24‐oic acid (deoxycholic acid DCA) is able to discriminate between the R ‐ and S ‐enantiomers of camphorquinone and endo ‐(+)‐3‐bromocamphor and select only the S ‐enantiomers from a racemic mixture. DCA forms novel well ordered 1:1 adducts with (1 S )‐(+)‐camphorquinone and (1 S )‐ endo ‐(‐)‐3‐bromocamphor, both of which have been characterized by single crystal X‐ray diffraction (SXRD). When DCA is cocrystallized with ( RS )‐camphorquinone and ( RS )‐ endo ‐3‐bromocamphor, 1:1 adducts of the S ‐enantiomers are produced together with crystals of the free racemic guest. In contrast, in the absence of (1 S )‐(+)‐camphorquinone, DCA forms a 2:1 adduct with (1 R )‐(−)‐camphorquinone. In this 2:1 adduct the guest is disordered at ambient temperature and undergoes a phase change in the region 160–130 K similar to that observed for the ferrocene adduct, but with only partial ordering of the guest. The SXRD structure of the low temperature form and the variable temperature 13 C CP/MAS NMR are reported. Cocrystallizing DCA with (1 R )‐ endo ‐(+)‐3‐bromocamphor gives the free guest and a glassy solid. Chirality, 2008. © 2008 Wiley‐Liss, Inc." @default.
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• W1964821644 date "2008-04-01" @default.
• W1964821644 modified "2023-10-17" @default.
• W1964821644 title "Discrimination of chiral guests by chiral channels: Variable temperature studies by SXRD and solid state13C NMR of the deoxycholic acid complexes of camphorquinone andendo-3-bromocamphor" @default.
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• W1964821644 doi "https://doi.org/10.1002/chir.20561" @default.
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