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- W1964848904 abstract "The energy of the lowest triplet state of organic molecules is intermediate between the ground state and the first excited singlet. At the S1/S0 conical intersection, the two singlet states are degenerate. It is shown that for some molecules (ethylene, benzene, toluene and pyrrole) the T1 state is also degenerate with the two singlet states. Moreover, the spin orbit coupling matrix element at this structure is necessarily large, so that intersystem crossing can be quite efficient. If the lowest triplet state is repulsive (as in the studied molecules) it may significantly contribute to the dissociation yield under certain experimental conditions." @default.
- W1964848904 created "2016-06-24" @default.
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- W1964848904 date "2007-08-01" @default.
- W1964848904 modified "2023-10-16" @default.
- W1964848904 title "Intersystem crossing at singlet conical intersections" @default.
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- W1964848904 doi "https://doi.org/10.1016/j.jphotochem.2007.02.005" @default.
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