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- W1964892810 abstract "Low Energy Electron Diffraction experiments have been performed on an ethane monolayer adsorbed on graphite single crystals for 70 < T < 85 K. The substep previously observed between the first and second layers on volumetric isotherms, at higher temperature, is identified as being the transition between an incommensurate phase I2 and a √3 × √3 commensurate solid phase S3. From photometric isotherms, the isosteric heat of adsorption has been determined (Qst = 7.6 ± 0.5 kcal/mol), in agreement with the previous measurements. From LEED patterns, it is shown that there is not only a first order jump in the lattice parameter at the incommensurate-commensurate transition, but also an abrupt change of 30° in the orientational epitaxy: S3 is 30° rotated with respect to the graphite axes; I2 is not rotated even when its parameter differs only by 3% from the S3 one. This striking behaviour may be due to the nature of I2 which could be a rather well correlated fluid like phase." @default.
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- W1964892810 date "1985-10-01" @default.
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- W1964892810 title "First order incommensurate-commensurate and rotational epitaxy transition in an ethane monolayer adsorbed on graphite: A leed study" @default.
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- W1964892810 doi "https://doi.org/10.1016/0039-6028(85)90932-x" @default.
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