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- W1964943489 abstract "The molecular structure of dimethyl ether—boron trifluoride (CH3)2O·BF3 has been studied at temperatures of 16, 30 and 70°C by gas-phase electron diffraction. The molecule exists in a staggered conformation with an O—B distance of 1.75 ± 0.02 Å, an angle between the O—B bond and the COC plane of 40 ± 8° and an FBF angle of 117 ± 2° at each temperature. However, the F—B and C—O distances are found to decrease with increasing temperature, and appear to converge to the corresponding values of the component molecules. The temperature dependence of the B—F and C—O distances is surprisingly large, compared with those in other molecules." @default.
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- W1964943489 date "1981-12-01" @default.
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- W1964943489 title "Temperature effects of the molecular structure of dimethyl ether—boron trifluoride as studied by gas-phase electron diffraction" @default.
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- W1964943489 doi "https://doi.org/10.1016/0022-2860(81)80071-3" @default.
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