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- W1964949860 abstract "Abstract A novel cobalt complex [Co(imi)6] · (NBA)2 · 2H2O (1), (imi = imidazole, NBA = 4-nitrobenzoic acid) has been hydrothermally synthesized and characterized by physical measurements and single-crystal X-ray diffraction techniques. The complex is triclinic, space group P1, with a = 8.0057(16), b = 9.2327(18), c = 13.618(3) Å, α = 95.89(3), β = 101.27(3), γ = 103.71(3), V = 947.2(3) Å3, Z = 1. In 1, the cobalt(II) ion is octahedral, coordinated by six nitrogen atoms from imidazole rings. An extensive three-dimensional supramolecular structure is formed via O–H ··· N and O–H ··· O hydrogen bonds between [Co(imi)6]2+ cations, NBA anions and water molecules, and π–π interactions between NBA molecules. Keywords: CobaltCrystal structureHydrothermal synthesisSupramolecular architecture Acknowledgements We gratefully acknowledge the financial support of the National Nature Science Foundation of China (Nos 50573030 and 50225313)." @default.
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- W1964949860 date "2007-02-10" @default.
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- W1964949860 title "Hydrothermal synthesis and structure of [Co(imi)<sub>6</sub>] <b>·</b> (NBA)<sub>2</sub> <b>·</b> 2H<sub>2</sub>O (imi <b>=</b> imidazole, NBA <b>=</b> 4-nitrobenzoic acid)" @default.
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- W1964949860 doi "https://doi.org/10.1080/00958970600763672" @default.
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