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- W1964967054 abstract "Although base-catalyzed addition of PhSH to PhCCCF, under thermodynamic control gives E-Ph(PhS)CCH(CF3), Z-Ph(PhO)CCH(CF3) is the thermodynamically favored product from similar reaction of PhOH with PhCCCF3. The preference for the cis-configuration of CF3 and PhO on a double bond is rationalized in terms of frontier orbital interactions." @default.
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- W1964967054 date "1986-01-01" @default.
- W1964967054 modified "2023-10-11" @default.
- W1964967054 title "On the role of the CF3 group in determining the relative stability of E, Z-isomers" @default.
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- W1964967054 doi "https://doi.org/10.1016/s0040-4039(00)84401-9" @default.
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