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- W1964974243 abstract "The micellization of the ionic liquid N-alkyl-N-methylpyrrolidinium bromide (CnMPB, n = 12, 14 and 16) in aqueous solutions was investigated by surface tension measurements, electrical conductivity and static luminescence quenching. The effectiveness of the surface tension reduction (Πcmc), maximum surface excess concentration (Γmax) and the minimum area (Amin) occupied per surfactant molecule at the air/water interface can be obtained from the surface tension measurements at 25 °C. The critical micelle concentration (cmc) at different temperatures and a series of thermodynamic parameters (ΔG0m, ΔH0m and ΔS0m) of micellization were evaluated from electrical conductivity measurements in the temperature range of 25–45 °C. The thermodynamic parameters show that the micelle formation is entropy-driven at low temperature and enthalpy-driven at high temperature. Furthermore, the micelle aggregation number (Nagg) of CnMPB was calculated according to the Turro-Yekta method through static luminescence quenching and found that Nagg (49, 55, and 59) increased with the hydrophobic chain length of CnMPB." @default.
- W1964974243 created "2016-06-24" @default.
- W1964974243 creator A5067597147 @default.
- W1964974243 creator A5077921764 @default.
- W1964974243 date "2011-01-01" @default.
- W1964974243 modified "2023-09-24" @default.
- W1964974243 title "Micelle formation by N-alkyl-N-methylpyrrolidinium bromide in aqueous solution" @default.
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- W1964974243 doi "https://doi.org/10.1039/c0cp00342e" @default.
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