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- W1965018502 abstract "The electrochemical behavior of anodically deposited manganese oxide was studied in pyrrolidinium formate (P-HCOO), 1-butyl-3-methylimidazolium hexafluorophosphate (BMI-PF6), and 1-ethyl-3-methylimidazolium thiocyanate (EMI-SCN) ionic liquids (ILs). The experimental data indicate that the Mn oxide electrode showed ideal pseudocapacitive performance in aprotic EMI-SCN IL. In a potential window of ∼1.5 V, the oxide specific capacitance, evaluated using cyclic voltammetry and chronopotentiometry, was about 55 F/g. The electrochemical energy storage reaction was examined using X-ray photoelectron spectroscopy (XPS). It was confirmed that the SCN− anions, instead of the EMI+ cations, were the primary working species that can become incorporated into the oxide and thus compensate the Mn3+/Mn4+ valent state variation upon the charge−discharge process. According to the analytical results, a pseudocapacitive mechanism of Mn oxide in the SCN− based aprotic IL was proposed." @default.
- W1965018502 created "2016-06-24" @default.
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- W1965018502 date "2009-07-21" @default.
- W1965018502 modified "2023-09-27" @default.
- W1965018502 title "Pseudocapacitive Mechanism of Manganese Oxide in 1-Ethyl-3-methylimidazolium Thiocyanate Ionic Liquid Electrolyte Studied Using X-ray Photoelectron Spectroscopy" @default.
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- W1965018502 doi "https://doi.org/10.1021/la9012119" @default.
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