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- W1965131567 abstract "Various models for binary liquid mixtures have led to equations explicitly relating the surface tension of these solutions to the surface tension of the pure components and the mole fraction of the solution. A recent treatment by Shereshefsky, however, improperly exploits his model and so is wrong in principle. The case of an ideal solution of equal-sized molecules is analyzed, and it is shown that the correct equation for this case is the equation of Belton and Evans. Shereshefsky's equation specialized to this case is incorrect and his results are shown to be inconsistent with the Gibbs adsorption theorem. The success of Shereshefsky's equation in representing surface tension of a number of binary pairs of liquids is shown to result from the rather narrow range of surface tensions covered using a three parameter equation; the Belton and Evans equation fits the same data, on the average, rather better. Since most of the pairs selected are nonideal, this result must also be regarded as largely fortuitous." @default.
- W1965131567 created "2016-06-24" @default.
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- W1965131567 date "1972-09-01" @default.
- W1965131567 modified "2023-09-28" @default.
- W1965131567 title "Surface tension of binary solutions of non-electrolytes" @default.
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- W1965131567 doi "https://doi.org/10.1016/0021-9797(72)90352-9" @default.
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