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- W1965133032 abstract "The chlorination of α-alumina with He–CO–Cl2 gas mixtures was investigated in the range 800–950°C. The kinetics of chlorination were determined using a thermogravimetric balance. The effect of reactant partial pressure on the chlorination kinetics was examined in detail. It would appear that the reaction is first-order with respect to each of the reactant gases, CO and Cl2. The temperature-variation of the apparent bimolecular rate constant K app (g.g.−1 min−l atm−2) for chlorination can be represented byln K app = − 0.169 (±0.267) − 3868(±300)/T.The apparent activation energy for the chlorination is thus seen to be 32 (± 2.5) kJ.mol−1 in the range 800–950°C." @default.
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- W1965133032 date "1987-07-01" @default.
- W1965133032 modified "2023-10-14" @default.
- W1965133032 title "Kinetics and Mechanism of Chlorination of Alumina Grains with He–CO–Cl2Gas Mixtures—I. Experimental" @default.
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- W1965133032 doi "https://doi.org/10.1179/cmq.1987.26.3.207" @default.
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