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- W1965133191 abstract "An efficient synthesis of di-π-([8]annulene)cerium(IV) (cerocene) is reported by the reaction of K[Ce(C8H8)2] with allyl bromide. Cerocenes can also be prepared by oxidation of the corrresponding cerates with silver iodide in THF, but this reaction is more variable. Cerocene reacts only slowly with UCl4 to give uranocene. K[Ce(C8H8)2] and cerocene undergo electron exchange on the NMR time scale. Electrochemical study of cerocene shows redox with the cerate ion, Ce(C8H8)2-, to be reversible with a relatively low reduction potential (−0.6 V vs NHE). The corresponding praeseodymium salt, K[Pr(C8H8)2], does not undergo comparable reversible oxidation; its cyclic voltammetry is compared with that of K2[Yb(C8H8)2]. The chemistry of cerocene resembles that of di-π-([8]annulene)actinide(IV) compounds." @default.
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- W1965133191 date "2004-09-18" @default.
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- W1965133191 title "Synthesis and Properties of Di-π-[8]annulenecerium(IV), Cerocene" @default.
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- W1965133191 doi "https://doi.org/10.1021/om049743+" @default.
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