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- W1965143174 abstract "Novel nonlinear optical (NLO) chromophore, 2-{3-[2-(4-methylsulfonylphenyl)vinyl]carbazol-9-yl}ethanol was synthesized and subsequently reacted with methacryloyl chloride to give a photoconducting NLO monomer (M1). 2-Methylacrylic acid 2-[3-(diphenylhydrazonomethyl)carbazol-9-yl]ethyl ester (M2) was also synthesized as a comonomer to enhance the carrier mobility of the NLO polymer. Photoconducting NLO polymers, P1 and P2 were obtained by the copolymerization of Ml with methyl methacrylate and M2, respectively. These polymers were well soluble in organic solvents and showed glass transition at 177 °C and 196 °C, respectively. Polymer films of P1 and P2 were optically clear, and were transparent at wavelengths longer than 420 nm. The electro-optic coefficient (r33) of poled P1 films was measured to be ∼5 pm/V at 632.8 nm. The photoconductive sensitivities of P1 and P2 were 6.2 × 10−14 S·cm−1/mW·cm−2 and 5.6 × 10−11 S·cm−1/mW·cm−2." @default.
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- W1965143174 date "1999-08-01" @default.
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- W1965143174 title "Synthesis of nonlinear optical polymers with large photoconductive sensitivity and transparency" @default.
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- W1965143174 doi "https://doi.org/10.1002/masy.19991420108" @default.
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