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- W1965220521 abstract "Polarized Raman spectra of a cytidine single crystal have been observed with 488.0 nm excitation by use of a Raman microscope. For each Raman band, the relative intensities of aa, bb, cc, ab and bc tensor components have been determined. The depolarization ratios were also determined in a cytidine solution. The shape and orientation of the local Raman tensor were deduced for each prominent Raman band, i.e. its principal axes and relative magnitudes of its components (r1 = αxxαzz, r2 = αyyαzz). The tensor for a strong Raman band at 1254 cm−1 was assumed to have the principal x axis along the N1-C4 line, the y axis along the N3-C5 line, and r1 = 13.2, r2 = −6.1. The tensor of the 793 cm−1 band was assumed to have a similar axis system, and r1 = 3.8, r2 = 3.2. The tensor of the anisotropic band at 603 cm−1 was assumed to have the principal x axis along the C2-N1 line, the y axis along the C2-C4 line, and r1 = −0.2, r2 = 20. Such information about the cytidine tensors is useful in determining the orientation of this residue in a biological fiber. As an example, a poly(rI)·poly(rC) duplex fiber has been subjected to an examination." @default.
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- W1965220521 date "1996-06-01" @default.
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- W1965220521 title "Local Raman tensors of cytidine and their orientations in poly(rI)·poly(rC)" @default.
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- W1965220521 doi "https://doi.org/10.1016/0022-2860(95)09175-0" @default.
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