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- W1965230355 abstract "The intermetallic rare-earth aluminide TbPdAl crystallizes in the hexagonal ZrNiAl-type structure (metastable high-temperature modification, HTM) and in the orthorhombic TiNiSi-type structure (stable low-temperature modification, LTM). Based on neutron diffraction, magnetic susceptibility and electrical resistivity data for TbPdAl we provide clear evidence for a first-order isostructural phase transition (from HTM I to HTM II), which is absent in the LTM phase, and determine the structural parameters for all three phases. For TbPdAl HTM jumps in the hexagonal lattice parameters a (decrease of 1.0%) and c (increase of 1.9%) occur at Tsh=106 K (heating) and Tsc=91 K (cooling), and the two phases HTM I and HTM II coexist with a volume fraction ≥20% in a temperature interval of 17 K. The structural phase transition is likely to be of electronic origin." @default.
- W1965230355 created "2016-06-24" @default.
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- W1965230355 date "1999-07-01" @default.
- W1965230355 modified "2023-09-24" @default.
- W1965230355 title "Evidence for an isostructural phase transition in the metastable high-temperature modification of TbPdAl" @default.
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- W1965230355 doi "https://doi.org/10.1016/s0925-8388(99)00157-7" @default.
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