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- W1965289010 abstract "Bis-niobocene (η5 : η1-C5H4)2Nb2H2 when treated with organic halides, e.g. C4H9Cl, C6H5CH2Cl, CCl4, CHCl3, CH3I and C2H5Br gives quantitatively new fulvalene complexes (η5 : η5-C10H8)(C5H5)2Nb2(μ-Hal). The complex (η5 :η5)-C10H8)(C5H5)2Nb2(μ-H)(μ-Cl) readily exchanges its bridging chlorine atom for methoxy and ethoxy groups or a hydride ligand. Reaction with water gives a diamagnetic compound, for which the structure (η5 : η5-C10H8)(C5H5)2(Cl)2Nb2(μ-O) is proposed. A new method for the synthesis of bis-niobocene through interaction of (C5H5)2NbCl2 with NaH in THF was found. It is shown that in DME the same reaction between (C5H5)2NbCl2 and NaH gives an isomeric fulvalene complex (η5 : η5-C10H8)(C5H5)2Nb2(μ-H)2 instead." @default.
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- W1965289010 date "1985-09-01" @default.
- W1965289010 modified "2023-09-23" @default.
- W1965289010 title "Synthesis and chemical properties of μ-hydrido-μ-halogenodicyclopentadienylfulvalenediniobium" @default.
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- W1965289010 doi "https://doi.org/10.1016/0022-328x(85)87336-8" @default.
- W1965289010 hasPublicationYear "1985" @default.
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