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• W1965322544 abstract "Abstract Oxazoline‐functionalized polypropylenes were synthesized by using the rac ‐Et[1‐Ind] 2 ZrCl 2 /MAO catalyst system. The used comonomers were 2‐(9‐decene‐1‐yl)‐1,3‐oxazoline (R‐Ox1), 2‐(9‐decene‐1‐yl)‐4,4‐dimethyl‐1,3‐oxazoline (R‐Ox2), and 2‐(4‐(10‐undecene‐1‐oxy)phenyl)‐1,3‐oxazoline (R‐Ox3). The oxazolines reduce the catalyst activity in the order R‐Ox3 > R‐Ox1 > R‐Ox2. By the addition of triisobutylaluminum (TIBA), the catalyst poisoning is reduced and is most pronounced in the R‐Ox1‐ and R‐Ox2‐containing systems. The oxazoline‐containing copolymers were melt blended with carboxylic acid end‐functionalized polystyrene (PS‐COOH) at 200°C. Strong changes in the morphology of the reactive blends compared to the nonreactive blends, especially the cocontinuous morphology in a poly(propylene‐ co ‐R‐Ox3)/PS‐COOH blend, indicate the usefulness of the modified copolymers in the reactive blending processes. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 2174–2181, 2002" @default.
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• W1965322544 date "2002-09-17" @default.
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• W1965322544 title "The effect of TIBA on metallocene/MAO catalyzed synthesis of propylene oxazoline copolymers and their use in reactive blending" @default.
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• W1965322544 doi "https://doi.org/10.1002/app.11161" @default.
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