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• W1965340837 abstract "Aus einem Vergleich der mesomeriebehinderten Chinuclidone I–III mit den ähnlich gebauten, aber mesomeriefähigen bicyclischen Lactamen V–VII werden Rückschlüsse auf den Anteil des Mesomerieeffektes an typischen Eigenschaften der Carbonamid-Funktion gezogen. Insbesondere werden die Basizitäten, die IR- und UV-Spektren, die Dipolmomente, die elektrophilen Reaktivitäten, das polarographische Verhalten und der H-D-Austausch an den aciden C-H-Bindungen diskutiert. A comparison of the quinuclid-2-ones (I–III) not capable of mesomeric interactions, with the structurally similar, mesomeric bicyclic lactams (V–VII) emphasizes the effect of mesomerism on the typical properties of the carbonamide function. The basicities, the IR and UV spectra, the dipole moments, the electrophilic reactivities, the polarographic behaviour and the H-D exchange of the acidic CH bonds are discussed." @default.
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• W1965340837 date "1965-01-01" @default.
• W1965340837 modified "2023-10-10" @default.
• W1965340837 title "Neues zur sterischen mesomeriehinderung bei lactamen vom typ des α-chinuclidons" @default.
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• W1965340837 doi "https://doi.org/10.1016/s0040-4020(01)93880-3" @default.
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