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- W1965352095 abstract "The versatility of the SAFT-VR approach in the prediction of fluid-phase equilibria of complex fluids is illustrated for systems of short and long hydrocarbons. In particular, we examine the vapor−liquid equilibrium of a mixture of methane + hexatriacontane (C36H74) and the adsorption and coadsorption of light alkanes on low-density polyethylene. The molecules are modeled as chains of square-well segments, and the approach incorporates separate contributions to take into account the effect of monomer−monomer interactions and the bonding of the segments to form chains. In previous work (McCabe, C.; Jackson, G. Phys. Chem. Chem. Phys. 1999, 1, 2057), the phase behavior of pure long-chain n-alkane molecules was examined using the SAFT-VR approach; the intermolecular potential parameters were found to tend to a limiting value as the chain length of the n-alkane increases. Linear relationships with molecular weight for these parameters are used to model the polyethylene polymer in this work." @default.
- W1965352095 created "2016-06-24" @default.
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- W1965352095 date "2001-07-28" @default.
- W1965352095 modified "2023-10-10" @default.
- W1965352095 title "Examining the Adsorption (Vapor−Liquid Equilibria) of Short-Chain Hydrocarbons in Low-Density Polyethylene with the SAFT-VR Approach" @default.
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- W1965352095 doi "https://doi.org/10.1021/ie0101386" @default.
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