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- W1965360770 endingPage "146" @default.
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- W1965360770 abstract "Herein we report on the syntheses, photophysico-chemical properties and nonlinear absorption parameters of bis-{1(4), 8(11), 15(18), 22(25)-(tetrapyridin-2-yloxy phthalocyaninato)} ytterbium (III) (3) and bis-{1(4), 8(11), 15(18), 22(25)-(tetrapyridin-4-yloxy phthalocyaninato)} ytterbium (III) (4). The fluorescence and singlet oxygen quantum yields obtained for complexes 3 and 4 are low. The triplet quantum yield obtained for complex 3 is high at ΦT = 0.89 whereas for complex 4 ΦT = 0.48. The third order optical susceptibility values are of the order: 10−11 esu (for complex 3), and 10−13 esu (for complex 4) while the hyperpolarizability values are of the order: 10−28 esu (for complex 3) and 10−31 esu (for complex 4). Complexes 3 and 4 show two-photon absorption coefficients of the order of 10−46 cm4 s/photon and 10−48 cm4 s/photon, and threshold intensities as low as 0.3 J cm−2 and 0.0045 J cm−2, respectively." @default.
- W1965360770 created "2016-06-24" @default.
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- W1965360770 date "2014-11-01" @default.
- W1965360770 modified "2023-10-16" @default.
- W1965360770 title "Synthesis of ytterbium bisphthalocyanines: Photophysicochemical properties and nonlinear absorption behavior" @default.
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- W1965360770 doi "https://doi.org/10.1016/j.optmat.2014.05.013" @default.
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