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• W1965367544 abstract "► Surface-modified SBA-15 helps synthesize SnO 2 particles smaller than pore diameter. ► 3.5 nm diameter SnO 2 nanoparticle within 6.3 nm pore prevents pore blockage. ► Smaller nanoparticles show faster degradation rate of rhodamine B dye. ► This emphasizes the importance of accessibility of dye molecule to SnO 2 surface. We address the accessibility of tin oxide (SnO 2 ) nanoparticles synthesized inside the pores of mesoporous silica (SBA-15) host. On using a low-temperature route for in situ synthesis of SnO 2 and hence eliminating interparticle aggregation, SnO 2 nanoparticles of diameter much smaller (3.5 nm) than the cylindrical pore diameter (6.3 nm) of the SBA-15 could be synthesized. This enables molecules diffusing into the SBA-15 pores to access the very high specific surface area of SnO 2 ; enabling the diffusing species to react easily with the latter. This is demonstrated by an enhanced photocatalytic degradation rate constant of an aqueous solution of rhodamine B dye, on contacting the latter with the SnO 2 -SBA-15 composite." @default.
• W1965367544 created "2016-06-24" @default.
• W1965367544 creator A5013390003 @default.
• W1965367544 creator A5054083986 @default.
• W1965367544 date "2012-02-01" @default.
• W1965367544 modified "2023-09-25" @default.
• W1965367544 title "Highly accessible SnO2 nanoparticle embedded SBA-15 mesoporous silica as a superior photocatalyst" @default.
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• W1965367544 doi "https://doi.org/10.1016/j.micromeso.2011.06.037" @default.
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