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- W1965392661 abstract "Pressure–area relations are derived for quasi-static compression of a Langmuir monolayer in the regimes of expanded and partially compressed chains. A monolayer is treated as an ensemble of flexible chains anchored at a flat water–air interface. Formation of surface pressure is attributed to excluded-volume interactions between segments of hydrophobic tail-groups. Close-form expressions are derived for the energy of interactions. Based on this relations, strength of excluded-volume interactions is evaluated by fitting pressure–area isotherms on stearic, behenic and pentacosadiynoic acids. It is found that the dimensionless strength of excluded-volume interactions is weakly affected by chain length and its value is close to 13." @default.
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- W1965392661 date "2007-08-01" @default.
- W1965392661 modified "2023-09-26" @default.
- W1965392661 title "Pressure–area relations for Langmuir monolayers" @default.
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- W1965392661 doi "https://doi.org/10.1016/j.eurpolymj.2007.05.022" @default.
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