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- W1965398335 abstract "Isothermal phase dissolution of phase-separated structures at different quench depths to one single temperature below the lower critical solution temperature was studied by the light scattering technique for different polymer blends. During the process of phase dissolution the light scattering intensity decays exponentially with time at a rate depending on an effective diffusion coefficient for the centre-of-mass motion of the chain molecules in the melt. The apparent diffusion coefficient varies as a function of the quench depth ΔT which indicates that the diffusion coefficient is directed by the thermodynamic driving force. With increasing ΔT the diffusion coefficient also increases initially. However, further increase of ΔT leads to a decrease of the diffusion coefficient. This is interpreted in terms of the interfacial free energy which contributes to the thermodynamic driving force." @default.
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- W1965398335 date "1989-09-01" @default.
- W1965398335 modified "2023-10-14" @default.
- W1965398335 title "Phase dissolution in polymer blends at different quench depths" @default.
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- W1965398335 doi "https://doi.org/10.1016/0032-3861(89)90334-0" @default.
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