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• W1965458370 endingPage "148" @default.
• W1965458370 startingPage "141" @default.
• W1965458370 abstract "Abstract The reaction of α‐fluorostyrene ( 1a ) with methyl phenyldiazoacetate in the presence of Rh 2 (OAc) 4 gave a 64:36 mixture of diastereomeric monofluorinated cyclopropanes 5a and 6a . When using chiral Rh II catalysts Rh 2 (TBSP) 4 ( 7 ) and Rh 2 (DOSP) 4 ( 8 ), the products were obtained enantioselectively in up to >99 % ee for both (1 R ,2 R )‐ 5a and (1 R ,2 S )‐ 6a . The fluorocyclopropane derivatives are of interest as dopants to induce chirality in liquid‐crystal mixtures. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)" @default.
• W1965458370 created "2016-06-24" @default.
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• W1965458370 date "2006-12-15" @default.
• W1965458370 modified "2023-10-18" @default.
• W1965458370 title "Synthesis of New Enantiopure Fluorinated Phenylcyclopropanecarboxylates – Potential Chiral Dopants for Liquid-Crystal Compositions" @default.
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• W1965458370 doi "https://doi.org/10.1002/ejoc.200600579" @default.
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