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- W1965473695 abstract "Abstract Two novel grid networks based on Keggin-type polyoxoanion, formulated [Cu(2,2′-bipy)2](HPMo12O40) · H2O (1) and [Cu(2,2′-bipy)2](HPW12O40) · H2O (2) have been synthesized hydrothermally and characterized by elemental analyses, IR, EPR and X-ray single crystal diffraction. 1 is a 2D grid network built by the interconnection of bisupporting polyoxoanion clusters assembled through weak Cu⋯O interactions. The EPR spectrum of 1 indicates that its unpaired electrons are placed in dx2−y2 orbital of the ground state of Cu(II). Compound 2 is isostructural with compound 1." @default.
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- W1965473695 date "2007-05-01" @default.
- W1965473695 modified "2023-09-23" @default.
- W1965473695 title "Two novel grid networks based on Keggin-type polyoxometalate clusters assembled through weak Cu⋯O interactions" @default.
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- W1965473695 doi "https://doi.org/10.1016/j.inoche.2007.01.024" @default.
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