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- W1965488001 abstract "A comparison of the electrochemical gating of molecular conduction by a redox [Os(bipyridine)(pyridine)Cl] complex tethered to Au(111) with two different metal−molecule junctions in a scanning tunneling microscope nanogap is presented. The same redox molecular structure was tethered by mercaptobenzoic acid or reduction of the aryldiazonium salt of p-aminobenzoic acid, resulting in a Au−S or Au−C bond, respectively. A two-step electron-transfer mechanism with vibrational relaxation of the redox molecule is apparent in each case." @default.
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- W1965488001 date "2009-12-02" @default.
- W1965488001 modified "2023-10-17" @default.
- W1965488001 title "Electrochemical Scanning Tunneling Spectroscopy of Redox-Active Molecules Bound by Au−C Bonds" @default.
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- W1965488001 doi "https://doi.org/10.1021/ja907867b" @default.
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