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- W1965495535 abstract "Abstract Structural parameters have been calculated for a number of molecules from the ground-state rotational constants. Near-equilibrium values have been obtained using the methods due to Costain and Pierce which are in essential agreement. Single-substitution calculations have been carried out on methane, ethylene and benzene, and the possibility of obtaining near-equilibrium configurations for these molecules is discussed. The equilibrium configurations, even when obtainable, are often subject to considerable uncertainty due to the complexity of the vibration-rotation problems, and in such cases rs parameters may be preferable to the re values." @default.
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- W1965495535 date "1961-01-01" @default.
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- W1965495535 title "Near-equilibrium bond distances in simple molecules" @default.
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- W1965495535 doi "https://doi.org/10.1016/0371-1951(61)80045-3" @default.
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