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- W1965500760 abstract "The thermal properties of coordination compounds of the composition Cu(NCS)2L2 (whereL=pyridine, 2-, 3- and 4-picoline, and 2,3-, 2,4-, 2,5-, 2,6-, 3,4- and 3,5-lutidine) are dealt with. The thermal decomposition of these compounds begins with the release of the ligandL. The compounds with pyridine derivatives containing a methyl substituent at position 2 show a markedly decreased initial decomposition temperature. It was found that X-ray irradiation caused a reduction of the central atom Cu(II) in the coordination compounds under investigation. X-ray electron spectra data showed the stability of the compounds Cu(NCS)2L2 withL=picoline or lutidine having a methyl substituent at position 2 to be distinctly lower in the surface layers. From the given series, the compounds Cu(NCS)2(pyridine)2 and Cu(NCS)2(3,5-lutidine)2 exhibit an analogous course of thermal decomposition in nitrogen atmosphere up to 600°. The stoichiometries of thermal decomposition are discussed." @default.
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- W1965500760 date "1978-02-01" @default.
- W1965500760 modified "2023-10-18" @default.
- W1965500760 title "Thermal properties of thiocyanatocopperc(II) complexes with picolines and lutidines" @default.
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- W1965500760 doi "https://doi.org/10.1007/bf01909908" @default.
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