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- W1965521848 abstract "Crystals of partially purified adamantane, in the presence of a substantial amount of water vapour, were grown under controlled conditions of temperature and supersaturation. The kinetics of growth of crystals on a glass substrate were studied, and the results analysed in terms of current theories. The nucleation behaviour depended upon the previous treatment of the substrate, and an explanation of this is put forward. The growth kinetics were quite well described by the Burton, Cabrera and Frank theory, but the activation energy for growth was roughly twice as large as expected. This discrepancy is explained in terms of the large impurity content of the system. Steps were seen on the faces of some crystals, and the movement of these steps could be partly accounted for using the BCF model. The value of the mean surface diffusion distance was larger than expected, which implies that surface diffusion is unlikely to be the rate controlling step in the growth kinetics. Crystals which had been evaporated to a small size, and then regrown, appeared to regrow by a somewhat different mechanism from the usual growth of a face. The activation energy for this regrowth was close to that predicted by the BCF theory for bulk growth." @default.
- W1965521848 created "2016-06-24" @default.
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- W1965521848 date "1984-08-01" @default.
- W1965521848 modified "2023-09-27" @default.
- W1965521848 title "The kinetics of growth of adamantane crystals from the vapour. II" @default.
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- W1965521848 doi "https://doi.org/10.1016/0022-0248(84)90047-2" @default.
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