FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1965561723> ?p ?o ?g. }

• W1965561723 endingPage "5309" @default.
• W1965561723 startingPage "5302" @default.
• W1965561723 abstract "The observed zero-point inertial defect Δ0=I0cc−I0aa−I0bb is often used as a test of the planarity of a molecule, but this test is difficult to make quantitative when the information on the vibrations and vibration–rotation interactions is limited. The general formula for the inertial defect to order κ2Ie is separated into harmonic and Coriolis contributions Δ0harm and Δ0Cor, which can be expressed in various ways by use of sum rules. It is shown here that the zero-point harmonic term is given approximately by Δharm0≊Δtau0= 3K(1/ωA+1/ωB+1/ωAB−1/ωC), where K is ℏ2/2hc and the effective vibrational frequencies are given in terms of the centrifugal tensor ταβγδ by τaaaa=−16A3/ωA2, τbbbb=−16B3/ωB2, τcccc=−16C3/ωC2, and τabab=−16ABC/ωAB2, so that Δ0harm can be estimated from centrifugal distortion constants. A fit of empirical data gives Δ0≊Δ0tau[1.0292−0.0911(N−3)], where N is the number of atoms and the correction factor makes approximate allowance for Δ0Cor. Thus an observed Δ0 that is significantly negative relative to this approximation may indicate that the molecule is nonplanar or has unusually low out-of-plane frequencies." @default.
• W1965561723 created "2016-06-24" @default.
• W1965561723 creator A5019896997 @default.
• W1965561723 date "1993-04-01" @default.
• W1965561723 modified "2023-10-18" @default.
• W1965561723 title "Approximations for the inertial defects of planar molecules" @default.
• W1965561723 cites W1972739298 @default.
• W1965561723 cites W1978184568 @default.
• W1965561723 cites W1979594228 @default.
• W1965561723 cites W1985879579 @default.
• W1965561723 cites W1989369885 @default.
• W1965561723 cites W2006892497 @default.
• W1965561723 cites W2008778933 @default.
• W1965561723 cites W2013265407 @default.
• W1965561723 cites W2014728666 @default.
• W1965561723 cites W2017134237 @default.
• W1965561723 cites W2022127010 @default.
• W1965561723 cites W2022162950 @default.
• W1965561723 cites W2023480901 @default.
• W1965561723 cites W2027949581 @default.
• W1965561723 cites W2028106601 @default.
• W1965561723 cites W2030058302 @default.
• W1965561723 cites W2049087496 @default.
• W1965561723 cites W2050691740 @default.
• W1965561723 cites W2053373732 @default.
• W1965561723 cites W2060935386 @default.
• W1965561723 cites W2061008826 @default.
• W1965561723 cites W2068191523 @default.
• W1965561723 cites W2069685076 @default.
• W1965561723 cites W2070089774 @default.
• W1965561723 cites W2070246755 @default.
• W1965561723 cites W2072885117 @default.
• W1965561723 cites W2076861346 @default.
• W1965561723 cites W2085455616 @default.
• W1965561723 cites W2085847994 @default.
• W1965561723 cites W2093938828 @default.
• W1965561723 cites W2312809634 @default.
• W1965561723 cites W3095389937 @default.
• W1965561723 cites W4232542998 @default.
• W1965561723 doi "https://doi.org/10.1063/1.464929" @default.
• W1965561723 hasPublicationYear "1993" @default.
• W1965561723 type Work @default.
• W1965561723 sameAs 1965561723 @default.
• W1965561723 citedByCount "32" @default.
• W1965561723 countsByYear W19655617232012 @default.
• W1965561723 countsByYear W19655617232013 @default.
• W1965561723 countsByYear W19655617232014 @default.
• W1965561723 countsByYear W19655617232015 @default.
• W1965561723 countsByYear W19655617232016 @default.
• W1965561723 countsByYear W19655617232020 @default.
• W1965561723 countsByYear W19655617232022 @default.
• W1965561723 countsByYear W19655617232023 @default.
• W1965561723 crossrefType "journal-article" @default.
• W1965561723 hasAuthorship W1965561723A5019896997 @default.
• W1965561723 hasConcept C121332964 @default.
• W1965561723 hasConcept C121684516 @default.
• W1965561723 hasConcept C127413603 @default.
• W1965561723 hasConcept C134306372 @default.
• W1965561723 hasConcept C134786449 @default.
• W1965561723 hasConcept C138885662 @default.
• W1965561723 hasConcept C155281189 @default.
• W1965561723 hasConcept C173386949 @default.
• W1965561723 hasConcept C17825722 @default.
• W1965561723 hasConcept C184779094 @default.
• W1965561723 hasConcept C185592680 @default.
• W1965561723 hasConcept C198394728 @default.
• W1965561723 hasConcept C2524010 @default.
• W1965561723 hasConcept C2779268580 @default.
• W1965561723 hasConcept C2780813799 @default.
• W1965561723 hasConcept C33923547 @default.
• W1965561723 hasConcept C40934718 @default.
• W1965561723 hasConcept C41008148 @default.
• W1965561723 hasConcept C41895202 @default.
• W1965561723 hasConcept C62520636 @default.
• W1965561723 hasConcept C68260962 @default.
• W1965561723 hasConcept C74650414 @default.
• W1965561723 hasConcept C78519656 @default.
• W1965561723 hasConcept C8010536 @default.
• W1965561723 hasConceptScore W1965561723C121332964 @default.
• W1965561723 hasConceptScore W1965561723C121684516 @default.
• W1965561723 hasConceptScore W1965561723C127413603 @default.
• W1965561723 hasConceptScore W1965561723C134306372 @default.
• W1965561723 hasConceptScore W1965561723C134786449 @default.
• W1965561723 hasConceptScore W1965561723C138885662 @default.
• W1965561723 hasConceptScore W1965561723C155281189 @default.
• W1965561723 hasConceptScore W1965561723C173386949 @default.
• W1965561723 hasConceptScore W1965561723C17825722 @default.
• W1965561723 hasConceptScore W1965561723C184779094 @default.
• W1965561723 hasConceptScore W1965561723C185592680 @default.
• W1965561723 hasConceptScore W1965561723C198394728 @default.
• W1965561723 hasConceptScore W1965561723C2524010 @default.
• W1965561723 hasConceptScore W1965561723C2779268580 @default.
• W1965561723 hasConceptScore W1965561723C2780813799 @default.
• W1965561723 hasConceptScore W1965561723C33923547 @default.
• W1965561723 hasConceptScore W1965561723C40934718 @default.
• W1965561723 hasConceptScore W1965561723C41008148 @default.
• W1965561723 hasConceptScore W1965561723C41895202 @default.
• W1965561723 hasConceptScore W1965561723C62520636 @default.

• next