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- W1965567105 abstract "An effective one-step C(sp2)-Si coupling reaction is presented in this article. Thus, monohydrosilanes can be easily prepared in a palladium-catalyzed reaction from dihydrosilanes and aryl and heteroaryl iodides. The method is general and can be applied for a large spectrum of electron-deficient and electron-rich aryl iodides. Functionalities, such as cyano goups and even amino and hydroxy groups are well tolerated. The authors suggest that the reaction may take place via σ-bond metathesis between the Pd(II) species and the aryl iodide. However, a pathway that would proceed via further oxidative addition resulting in the formation of a Pd(IV) species cannot be excluded." @default.
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- W1965567105 date "2007-12-18" @default.
- W1965567105 modified "2023-09-27" @default.
- W1965567105 title "Palladium-Catalyzed Si-C(sp2) Bond Formation for the Preparation of Monohydrosilanes" @default.
- W1965567105 doi "https://doi.org/10.1055/s-2007-991439" @default.
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