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• W1965569522 endingPage "3452" @default.
• W1965569522 startingPage "3445" @default.
• W1965569522 abstract "The ligand tris[3-(4-methoxyphenyl)-5-methylpyrazol-1-ylmethyl]amine (L), the copper(II) complexes [CuLCl2] 1, [CuLCl][SbF6] 2 and [CuL(H2O)][SbF6]23, and the copper(I) complex [CuL][CF3SO3] 4 have been prepared. Complexes 1–3 are reduced by [BPh4]− ion in a range of solvents to afford [CuL]+ ion. The [CuL]+ ion does not react with dioxygen nor carbon monoxide but does react with chloride ion. Physicochemical and cyclic voltammetry data are reported for 1–4, along with crystal structure analyses of 1–3 and [CuL][CuCl2]. There are some notable differences between the structures and properties of these copper complexes and those reported for analogues with pyridyl- or imidazolyl amine ligands." @default.
• W1965569522 created "2016-06-24" @default.
• W1965569522 creator A5060461853 @default.
• W1965569522 creator A5061275029 @default.
• W1965569522 creator A5071544355 @default.
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• W1965569522 date "2000-01-01" @default.
• W1965569522 modified "2023-09-24" @default.
• W1965569522 title "Copper(II/I) complexes of a bulky tris(pyrazolylmethyl)amine ligand" @default.
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• W1965569522 doi "https://doi.org/10.1039/b005081o" @default.
• W1965569522 hasPublicationYear "2000" @default.
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