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- W1965588596 abstract "Abstract A series of new red-emitting BaCa 1-2 x BO 3 F: x Eu 3+ , x M + (M=Li, Na, K) phosphors were synthesized by the solid-reaction method. X-ray diffraction (XRD), diffuse reflection (UV-vis) and photoluminescence spectra were utilized to characterize the crystallization process, structure and luminescence properties of the as-synthesized phosphors. The XRD results indicated that the sample began to crystallize at 800 °C, and single-phase BaCaBO 3 F was fully obtained after annealing at 1000 °C. The charge compensated behaviors were investigated in this paper by considering different cations like Li + , Na + and K + acting as the charge compensator. The as-prepared phosphors had better emission properties, and the two characteristic emission lines peaking at 590 and 615 nm could be obtained upon 394, 463 and 532 nm excitation with the chromaticity coordinates of (0.596, 0.391), which were due to 5 D 0 - 7 F 1 and 5 D 0 - 7 F 2 transitions of Eu 3+ ions. Further, the concentration quenching and corresponding luminescence mechanisms of BaCa 1-2 x BO 3 F: x Eu 3+ , x Na + phosphors were also discussed." @default.
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- W1965588596 date "2011-04-01" @default.
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- W1965588596 title "Luminescence properties of a new red emitting Eu3+-doped alkaline-earth fluoborate phosphor: BaCa(1-2x)BO3F:xEu3+, xM+ (M=Li, Na, K)" @default.
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- W1965588596 doi "https://doi.org/10.1016/s1002-0721(10)60452-8" @default.
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