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- W1965600244 abstract "Complementary selectivity can be achieved in ring opening reactions of 2-aziridinemethanols by using either the Gilman reagent or lower order cyanocuprate. In the former case, the usual attack of the Gilman reagent to the substrates 1 and 2 results in the formation of the expected ring opening products (3 and 4) and (7 and 8), respectively. In contrast, exposure of both 1 and 2 to the lower order cyanocuprate proceeds in an unprecedented fashion, presumably via epoxides D and G, to yield unexpected secondary alcohols (11 and 12) as the major products." @default.
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- W1965600244 date "1993-11-01" @default.
- W1965600244 modified "2023-10-10" @default.
- W1965600244 title "Unprecedented rearrangement reaction of 2-aziridinemethanols with “lower order” lithium methylcyanocuprate" @default.
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- W1965600244 doi "https://doi.org/10.1016/s0040-4039(00)60142-9" @default.
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