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- W1965620904 endingPage "4122" @default.
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- W1965620904 abstract "A new pyridyl-carboxylate ligand, the anion of trans-4-cotininecarboxylic acid, HL, 1, has been used to prepare a new polymeric copper(II) complex, [CuLN3]2n, 2, based on a [CuLN3]2 dimeric building block. The single crystal structures of both 1 and 2 have been determined and 1 has been found to be in its zwitterionic configuration. The structure of 2 is a one-dimensional tape-like polymeric structure based on an end-on azido-bridged binuclear [Cu2N3]2 backbone moiety. Magnetic studies reveal that 2 is close to paramagnetic from 2 to 300 K with a Curie constant of 1.094 emu K/mol, a Weiss temperature of 0.73 K and a corresponding μeff of 2.09 μB. A fit of χMT for 2 with S1 = S2 = ½, yields g = 2.441(6), J = −0.49(3) cm−1, zJ = −0.38(2) cm−1 and N(α) = 0.00053(12) emu/mol, a fit that indicates the presence of both very weak intramolecular intrachain antiferromagnetic exchange coupling within the one-dimensional tape-like chains and very weak interchain antiferromagnetic exchange coupling between these chains." @default.
- W1965620904 created "2016-06-24" @default.
- W1965620904 creator A5006758709 @default.
- W1965620904 creator A5007896601 @default.
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- W1965620904 date "2010-11-01" @default.
- W1965620904 modified "2023-10-04" @default.
- W1965620904 title "The use of trans-4-cotininecarboxylate to construct a polymeric copper(II) azido complex: Hydro(solvo)thermal synthesis, structure and magnetic properties" @default.
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- W1965620904 doi "https://doi.org/10.1016/j.ica.2010.05.002" @default.
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