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• W1965629406 endingPage "2124" @default.
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• W1965629406 abstract "A dinuclear platinum(II) complex of (dfppy)2Pt2(dipic) has been prepared, where dfppy is 2,4-difluorophenylpyridine and dipic is a biphenyl-bridged bi-picolinic acid derivative. Its physical and optoelectronic properties, as well as molecular orbitals calculation have been investigated and compared with those of its mono-nuclear (dfppy)Pt(pic) complex. Both platinum(II) complexes exhibited almost identical photoluminescence (PL) spectra with deep blue emission in dilute dichloro-methane (10−5 M) and different PL spectra with red emission in their neat films. Stable white emissions were obtained in the (dfppy)2Pt2(dipic)-doped polymer light-emitting devices using a blend of poly(vinylcarbazole) and 2-(4-biphenyl)-5-(4-tert-butyl-phenyl)-1,3,4-oxadiazole as a host matrix at dopant concentrations from 1 wt % to 10 wt %. In contrast, the (dfppy)Pt(pic)-doped devices exhibited orange-red emissions in the same device configuration. It indicates that dinuclear platinum(II) complex with a non-planar structure is an effective way to control formation excimers of platinum(II) complex and get white-emitting PLEDs with single dopant." @default.
• W1965629406 created "2016-06-24" @default.
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• W1965629406 date "2011-03-01" @default.
• W1965629406 modified "2023-09-27" @default.
• W1965629406 title "White emission from dinuclear cyclometalated platinum(II) complex in single-emitting layer PLEDs" @default.
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• W1965629406 doi "https://doi.org/10.1016/j.tet.2011.01.042" @default.
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