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- W1965652155 abstract "The 14N nuclear quadrupole resonance spectra have been measured for nitrobenzene and nine substituted nitrobenzenes. The experiments were carried out at 77 K, using the double-resonance, level-crossing technique. The 14N signals for the −NH2 groups of m-and p-nitroaniline were also observed. The quadrupole coupling constants for the nitro group nitrogens vary from 1493 kHz for p-nitroaniline (η = 0.292) to 1232 kHz for m-dinitrobenzene (η = 0.360). The dependence of e2Qq/h upon the meta or the para substituent suggests that the substituents affect mainly the covalency in the nitrogen-carbon σ bond. A linear relationship is observed between e2Qq/h and the Hammett substituent constants." @default.
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- W1965652155 date "1977-12-01" @default.
- W1965652155 modified "2023-09-23" @default.
- W1965652155 title "Nitrogen-14 nuclear quadrupole resonance spectra of substituted nitrobenzenes" @default.
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- W1965652155 doi "https://doi.org/10.1016/0022-2364(77)90280-3" @default.
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