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• W1965656610 startingPage "163" @default.
• W1965656610 abstract "Abstract We report a gradient wettability surface on copper slide prepared by a simple controlled ester group hydrolysis procedure of poly(methyl methacrylate–butyl acrylate) [P (MMA-BA)] films coated on the copper substrate. In the method, sodium hydroxide solutions are selected to prepare surface gradient wettability on P (MMA-BA) films. The P (MMA-BA) copolymers with different MMA contents are first synthesized by a conventional free atom radical solution polymerization method. The transfer of surface chemical composition from the ester group to acid salt is achieved by hydrolysis in NaOH solution. The effects of different concentrations of NaOH solution and reaction times on the physicochemical properties of the resulting surfaces are studied. The field-emission scanning electron microscopy (FESEM), atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS) results show that the varying concentration along the substrate length is only attributed to the hydrolysis reaction of ester groups. The hydrolysis causes insignificant change on the morphology of the original film on the copper substrate. In addition, it is found that the MMA copolymer content has a significant influence on the concentration of ester groups on the outermost surface and thus important for forming the slope gradients." @default.
• W1965656610 created "2016-06-24" @default.
• W1965656610 creator A5006449515 @default.
• W1965656610 creator A5043938283 @default.
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• W1965656610 date "2014-10-01" @default.
• W1965656610 modified "2023-09-26" @default.
• W1965656610 title "Construction of wettability gradient surface on copper substrate by controlled hydrolysis of poly(methyl methacrylate–butyl acrylate) films" @default.
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• W1965656610 doi "https://doi.org/10.1016/j.apsusc.2014.07.045" @default.
• W1965656610 hasPublicationYear "2014" @default.
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