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- W1965697391 abstract "ESR of P2O5-doped V2O5 single crystals shows that paramagnetic defect of V2O5 can be modified by adding small amounts of P2O5. Instead of being equally delocalized over two vanadium sites, the unpaired electron appears to be mostly localized on a single vanadium. Smaller hyperfine couplings are observed with another vanadium and one phosphorus nucleus. This suggests that PO4 tetrahedra are inserted between two a, c cleavage planes, where they take the place of an apex oxygen in the VO5 basic pyramid. Les monocristaux de V2O5 dopes avec P2O5 ont été étudiés par RPE. Le défaut paramagnétique existant dam V2O5 pur se trouve complètement modifié par l'addition de faibles quantités de P205. L'électron paramagnétique n'est plus localisé sur deux sites vanadium mais se trouve principalement en interaction avec un seul vanadium. On observe egalement un faible couplage hyperfin avec un deuxième vanadium et un phosphore. Ceci permet de suggérer que le tétraèdre PO4 est inseré entre deux plans de clivage a, c de la structure orthorombique de V2O5 et se substitue à l'oxygène situé au sommet de la pyramide de base formant cette structure." @default.
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- W1965697391 date "1981-07-16" @default.
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- W1965697391 title "ESR of P2O5-doped V2O5 single crystals" @default.
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- W1965697391 doi "https://doi.org/10.1002/pssa.2210660133" @default.
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