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• W1965710557 abstract "Abstract M(HL)(H 2 O) n complexes have been obtained by the electrochemical reaction of Fe, Co, Ni, Cu, Zn and Cd anodes with the potentially pentadentate and trianionic asymmetrical Schiff base 3‐aza‐ N ‐{2‐[1‐aza‐2‐(5‐nitro‐2‐hydroxylphenyl)‐vinyl]phenyl}‐4‐(5‐nitro‐2‐hydroxyphenyl)but‐3‐enamide (H 3 L), containing a hard amido donor atom. The complexes have been characterized by elemental analysis, mass spectrometry, IR and 1 H NMR spectroscopies, magnetic measurements and molar conductivities. Co(HL)(H 2 O) ( 2 ) has been found to rearrange in DMF solution into a crystallographically solved octahedral complex, CoL 1 (H 2 O) 2 ( 7 ) [where H 2 L 1 is the symmetrical Schiff base ligand N,N′ ‐(1,2‐phenylene)‐bis(5‐nitro‐3‐hydroxysalicylidenimine)]. A hydrolysis mechanism is discussed to explain this rearrangement." @default.
• W1965710557 created "2016-06-24" @default.
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• W1965710557 date "2005-08-01" @default.
• W1965710557 modified "2023-10-18" @default.
• W1965710557 title "Electrochemical Synthesis of MII Complexes with a Schiff Base containing an Amido Group. Crystal Structure of a Cobalt(II) Complex with a Reorganised Ligand" @default.
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• W1965710557 doi "https://doi.org/10.1002/zaac.200570034" @default.
• W1965710557 hasPublicationYear "2005" @default.
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